Introduction to Alkenes

  • Definition and structure of alkenes

  • Importance and applications in organic chemistry

II. Electrophilic Addition Reactions

  • Overview of electrophilic addition mechanism

  • Why alkenes are susceptible to electrophilic attack

III. Addition of HBr to Alkenes

  • Detailed mechanism of the addition reaction

  • Role of bromonium ion formation

  • Stereochemistry considerations

IV. Markovnikov's Rule

  • Explanation of Markovnikov's rule

  • Application to addition of HBr to alkenes

  • Examples and practice problems

V. Anti-Markovnikov Addition

  • Introduction to Anti-Markovnikov addition

  • Mechanism and its significance

  • Cases where Anti-Markovnikov addition occurs

VI. Factors Affecting Markovnikov vs. Anti-Markovnikov Addition

  • Impact of peroxide (ROOR) in HBr addition

  • Radical mechanism overview

  • Stereochemical outcomes

VII. Practical Applications and Examples

  • Real-world examples illustrating Markovnikov and Anti-Markovnikov additions

  • Chemical synthesis implications

VIII. Conclusion

  • Recap of key points discussed

  • Importance of understanding alkene reactions in organic synthesis

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